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32.
Fuqi Chen Rogemar Mamon Sévérien Nkurunziza 《Annals of the Institute of Statistical Mathematics》2018,70(4):807-853
Determining accurately when regime and structural changes occur in various time-series data is critical in many social and natural sciences. We develop and show further the equivalence of two consistent estimation techniques in locating the change point under the framework of a generalised version of the one-dimensional Ornstein–Uhlenbeck process. Our methods are based on the least sum of squared error and the maximum log-likelihood approaches. The case where both the existence and the location of the change point are unknown is investigated and an informational methodology is employed to address these issues. Numerical illustrations are presented to assess the methods’ performance. 相似文献
33.
Can Li Dr. Zheng Yang Lei Wang Prof. Dr. Yinlong Guo Prof. Dr. Zheng Huang Prof. Dr. Shengming Ma 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(15):6337-6342
An efficient pincer-ligand-based cobalt-complex-catalyzed allene hydroboration affording Z-allylic boronates is described. The reaction demonstrates an excellent regio- as well as Z-stereoselectivity and a wide substrate scope that tolerates many functional groups. Based on solvent-assisted electrospray ionization mass spectrometry (SAESI-MS) studies, a rationale for the cobalt-catalyzed hydroboration involving the highly selective insertion of an allene into the Co−H bond to form Z-allylic cobalt intermediates is proposed. 相似文献
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In this paper, by linking Fokker–Planck equations with stochastic coupled systems, a new method is provided to investigate the existence of a stationary distribution of stochastic coupled systems. Based on the graph theory and the Lyapunov method, an appropriate Lyapunov function associated with stationary Fokker–Planck equations is constructed. Moreover, a Lyapunov-type theorem and a coefficients-type criterion are obtained to guarantee the existence of a stationary distribution. Furthermore, theoretical results are applied to explore the existence of a stationary distribution of stochastic predator–prey models with dispersal and a sufficient criterion is presented correspondingly. Finally, a numerical example is given to illustrate the effectiveness of our results. 相似文献
37.
Jian-Kun Sun Linlin Zhang Liang Yue Tang Tang Wen-Jie Jiang Yun Zhang Zhenxiao Pan Xinhua Zhong Jin-Song Hu Li-Jun Wan 《中国科学:化学(英文版)》2018,61(10):1338-1344
Developing efficient counter electrodes (CEs) and quantum dots made of earth-abundant and non-toxic elements is essential but still challenging for quantum dot-sensitized solar cells (QDSSCs). Here, we report a facile strategy to prepare self-supported and robust CoS2 and NiS nanocrystals-assembled nanosheets directly grown on carbon paper (MSx NS@CP) as efficient counter electrodes for QDSSCs. Such CEs integrate the merits of fast electron transfer from interconnected conductive scaffold, efficient mass transfer from hierarchically vertical nanosheet on 3D open substrate, as well as abundant highly active catalytic sites from metal sulphide nanocrystal units. As a result, QDDSCs based on such CoS2 NS@CP and NiS NS@CP CEs achieve a PCE of 8.88% and 7.53%, respectively. The detailed analyses suggest that CoS2 NS@CP has the highest catalytic activity and shows the lowest charger transfer resistance, leading to the highest PCE. These findings may inspire the design and exploration of other self-supported efficient CEs by integrating highly active catalysts onto 3D conductive networks for efficient QDSSCs. 相似文献
38.
Chen Zhao Zifeng Chen Wei Wang Peixun Xiong Benfang Li Mengjie Li Dr. Jixing Yang Prof. Yunhua Xu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(29):12090-12096
Organic cathode materials have attracted extensive attention because of their diverse structures, facile synthesis, and environmental friendliness. However, they often suffer from insufficient cycling stability caused by the dissolution problem, poor rate performance, and low voltages. An in situ electropolymerization method was developed to stabilize and enhance organic cathodes for lithium batteries. 4,4′,4′′-Tris(carbazol-9-yl)-triphenylamine (TCTA) was employed because carbazole groups can be polymerized under an electric field and they may serve as high-voltage redox-active centers. The electropolymerized TCTA electrodes demonstrated excellent electrochemical performance with a high discharge voltage of 3.95 V, ultrafast rate capability of 20 A g−1, and a long cycle life of 5000 cycles. Our findings provide a new strategy to address the dissolution issue and they explore the molecular design of organic electrode materials for use in rechargeable batteries. 相似文献
39.
Jin Chen Dr. Chun-Li Hu Xiao-Han Zhang Dr. Bing-Xuan Li Dr. Bing-Ping Yang Prof. Jiang-Gao Mao 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(13):5419-5422
The first alkali-metal vanadium iodate fluoride, CsVO2F(IO3), with a novel 3D anionic framework, has been rationally designed and hydrothermally synthesized. The 3D [VO2F(IO3)]− framework in CsVO2F(IO3) is built from 0D Λ-shaped cis-[VO3F(IO3)2]4− polyanions via corner-sharing of oxo anions and bridging of the iodate groups. CsVO2F(IO3) displays both a strong second-harmonic generation (SHG) 1.1 times as strong as KTiOPO4 (KTP) under 2.05 μm laser radiation and high laser-induced damage threshold (LIDT) of 107.9 MW cm−2. This work provides a new route to design SHG crystals with stable 3D anionic structures from low-dimensional structural building units. 相似文献
40.
Dual-phase-lag equation for heat conduction is analyzed from the point of view of non-equilibrium thermodynamics. Its first-order Taylor series expansion is consistent with the second law as long as the two relaxation times are not negative. 相似文献